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Abstract
The objective of the present study was to study equilibrium isotherm for the sorption of Nickel ions onto coal fly ash. In this study, BET adsorption isotherm was found to be best fitted among Langmuir, Freundlich, BET, Temkin and Harkins Jura adsorption isotherms using lest square fit method. The best fit adsorption isotherm is assessed by the linear coefficient of determination (R2) and non-linear Chi-square test. The theoretical value of qe calculated from the best fit linear equation of each adsorption isotherm and the experimental values of qe (0.08) are plotted against Ce, to compare the experimental and Theoretical value of qe.
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References
- Al-Asheh, S. and Duvnjak, Z. 1997. Sorption of cadmium and other heavy metals by pine bark, Advance Environment Research, 1: 194.
- Bagdonavicius, V. and Nikulin, M.S. 2011. Chi-square goodness-of-fit test for right censored data, The International Journal of Applied Mathematics and Statistics, 30-50.
- Brunauer, S., Emmett, P. H. and Teller, E. 1938. Adsorption of gases in multi molecular layers, Journal of American Chemical Societ, 60: 309–319.
- Chatterjee S., Dae S. L., Lee, M. W. and Seung H. W. 2009. Enhanced adsorption of congo red from aqueous solutions by chitosan hydrogel beads impregnated with cetyl trimethyl ammonium bromide, Bioresource Technoology, 100: 2803–2809
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- Freundlich, H. 1906. Adsorption in solution, Physical Chemistry, 57: 384–410.
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- Harkins, W. D. and Jura, G. 1944. A vapor adsorption Method for the determination of the Area of a Solid without the Assumption of Molecular Area, and the Areas Occupied by Nitrogen and Other Molecules on the Surface of a Solid, Journal of American Chemical Society, 66: 1366-1377.
- Krishnan, K. A. and Anirudhan, T. S. 2002. Removal of mercury (II) from aqueous solutions and chlor-alkali industry effluent by steam activated and sulphurised activated carbons prepared from bagasse pith: Kinetics and equilibrium studies, Journal of Hazardous Materials, B 92: 161-183.
- Langmuir, I. 1918. Adsorption of gases on plane surfaces of glass, mica and platinum, Journal of American Chemical Society, 40: 1361-1403.
- Njoku, C. and Ngene, P. N. 2012. Content and Distribution of Heavy Metals in an Abandoned Mechanic and Non-Mechanic Sites in Abakaliki, Southeastern Nigeria, Greener Journal of Physical Science, 2(1): 016-019.
- Pourkhorshidi, A. R., Najimi, M., Parhizkar, T., Jafarpour, F. and Hillemeier, B. 2010. Applicability of the standard specifications of ASTM C618 for evaluation of natural pozzolans, Cement Concrete Composition, 32(10): 794–800.
- Reeve, D. J. 2007. Environmental improvements in the metal finishing industry, Journal of Cleaner Production, 15(8–9): 756–763.
- Takaoka, M., Kawai, T., Takeda, N. and Oshita, K. 2002. Recovery of Heavy Metals in Fly ash from Ash Melting Furnace by Solvent Extraction, Proceedings of Environmental Engineering Research, 39: 403-412.
- Tempkin, M. I. and Pyzhev, V. 1940. Kinetics of ammonia synthesis on promoted iron catalyst, Acta Physica Chimica., USSR 12: 327
References
Al-Asheh, S. and Duvnjak, Z. 1997. Sorption of cadmium and other heavy metals by pine bark, Advance Environment Research, 1: 194.
Bagdonavicius, V. and Nikulin, M.S. 2011. Chi-square goodness-of-fit test for right censored data, The International Journal of Applied Mathematics and Statistics, 30-50.
Brunauer, S., Emmett, P. H. and Teller, E. 1938. Adsorption of gases in multi molecular layers, Journal of American Chemical Societ, 60: 309–319.
Chatterjee S., Dae S. L., Lee, M. W. and Seung H. W. 2009. Enhanced adsorption of congo red from aqueous solutions by chitosan hydrogel beads impregnated with cetyl trimethyl ammonium bromide, Bioresource Technoology, 100: 2803–2809
Devarly, P., Liu, J. C., Suryadi, I. and Wang, M. J. 2012. Adsorption of Tetramethylammonium Hydroxide on Activated Carbon, Journal of Environmental Engineering -ASCE 138:232-238.
Fattahpour, S. I., Igsell, P., Ringqvist, L. and Lindström, E. B. 1996. Comparison of metal adsorption properties and determination of metal adsorption capacities of different peat samples, Resource and Environmental Bio technology, 1: 111–128.
Freundlich, H. 1906. Adsorption in solution, Physical Chemistry, 57: 384–410.
Gupta, G. and Torres, N. 1998. Use of fly ash in reducing toxicity of and heavy metals in wastewater effluent , Journal of Hazardous Materials, 57(1-3): 243-248.
Harkins, W. D. and Jura, G. 1944. A vapor adsorption Method for the determination of the Area of a Solid without the Assumption of Molecular Area, and the Areas Occupied by Nitrogen and Other Molecules on the Surface of a Solid, Journal of American Chemical Society, 66: 1366-1377.
Krishnan, K. A. and Anirudhan, T. S. 2002. Removal of mercury (II) from aqueous solutions and chlor-alkali industry effluent by steam activated and sulphurised activated carbons prepared from bagasse pith: Kinetics and equilibrium studies, Journal of Hazardous Materials, B 92: 161-183.
Langmuir, I. 1918. Adsorption of gases on plane surfaces of glass, mica and platinum, Journal of American Chemical Society, 40: 1361-1403.
Njoku, C. and Ngene, P. N. 2012. Content and Distribution of Heavy Metals in an Abandoned Mechanic and Non-Mechanic Sites in Abakaliki, Southeastern Nigeria, Greener Journal of Physical Science, 2(1): 016-019.
Pourkhorshidi, A. R., Najimi, M., Parhizkar, T., Jafarpour, F. and Hillemeier, B. 2010. Applicability of the standard specifications of ASTM C618 for evaluation of natural pozzolans, Cement Concrete Composition, 32(10): 794–800.
Reeve, D. J. 2007. Environmental improvements in the metal finishing industry, Journal of Cleaner Production, 15(8–9): 756–763.
Takaoka, M., Kawai, T., Takeda, N. and Oshita, K. 2002. Recovery of Heavy Metals in Fly ash from Ash Melting Furnace by Solvent Extraction, Proceedings of Environmental Engineering Research, 39: 403-412.
Tempkin, M. I. and Pyzhev, V. 1940. Kinetics of ammonia synthesis on promoted iron catalyst, Acta Physica Chimica., USSR 12: 327