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Abstract
Synthetic Pyrethroids are the new major class of broad spectrum organic insecticides used in Agriculture. Among the Pyrethroids, Fenvalerate (RS a cyano 3 Phenoxy Benzyl RS 2-{4 Chlorophenyl ] 3-Metyl Butyrate) is used extensively and is most effective Pyrethroid. The technical isomer is a mixture of four optical isomers 2 S, a S, 2R and a S. The 2S isomers are more toxic than 2R. They are toxic to aquatic organisms. When they are being transported into aquatic environment. The toxic action of the toxicant will depend on metabolism and mode of action in aquatic organism. Hence to study it static and continuous flow through tests were conducted to determine LCso values to the freshwater fish. The possible mechanism of toxic action will be presented.
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References
- Anita Susan T., Veeeraiah K. and Tilak K. S. 1999 a. Biochemical changes in the tissues of the fish Catla catla exposed to fenvaleratse a syntheticpyrethroid. J. Ecobiology 1102), 109-116.
- Anita Susan T., Veeraiah K. and Tilak K. S. 1999 b. A study on the Bioaccumulation ofFenvalerate a synthetic pyrethroid in the whole body tissue ofLabeo rohita, Catla catla, Cirrhinus mrigala by GLC. Enviromedia 18(1), 57-59.
- Amon 1975. Committee on Methods of Toxicity Tests with Fish, Macroinvertebrates and Amphibuians EPA Oregon 61 pp.
- Bradbury S. P. and Coats J. R. 1982. Toxicity of fenvalerat4e to bobwhite quail including brain and liver residues associated with mortality. J. Toxicol. & Environ. Health. 10, 307-319. DOI: https://doi.org/10.1080/15287398209530253
- Bradbury S. P., Coats J. R. and Mckim J. M. 1985. Differential toxicity and uptake of two fenvalerate formulation in fathead minoows ( Pimephales promelas) Environ. Toxicol. Chem. 4, 533-541. DOI: https://doi.org/10.1002/etc.5620040413
- Bradbury S. P., Coats J. R., Mc Kim J . M . 1986. Toxicokinetics offenvalerate in rainbow trout Salmo gairdneri. Environ. Toxicol Chem. 5, 567- 576. DOI: https://doi.org/10.1002/etc.5620050609
- Bradbury S. P., McKim J. M. and Coats J. R. 1987. Physiological response of rainbow torut to acute fenvalerate intoxificatin. Pestic Biochem. Physiol. 27, 275-288. DOI: https://doi.org/10.1016/0048-3575(87)90057-5
- Coats J. R. and O'D Jefery N. 1979. Toxicity of four synthetic pyrethroid insecticides to rainbow trout. Bull Environ. Cont@m. Toxicol. 23, 250 -255. DOI: https://doi.org/10.1007/BF01769951
- Demoute J. P. 1989. A brief review of the environmental fate and metabolism ofpyrethroids. Pestie. Science. 27,375-385. DOI: https://doi.org/10.1002/ps.2780270406
- Edwards R. and Millburn P. 1985. The metaboism and toxicity of insecticides in fish. In: Hutson D. H. and Roberts T. R. (eds) Progress in Pesticides Biochemistry and Toxicology Vo/.5. Insecticides John Wiley and Sons Ltd., New York, pp. 249-274.
- Finney D. J. 1971. Probit Analysis. Cambridge University Press, 333pp.
- Haya K.1989. Toxicity ofpyrethroid insecticides to fish. Environ. Toxicol. Chem.. 8, 381-391. Murty A. S. 1986. Toxicity ofPesticides to Fish vol. I & II. CRC Press, Inc. DOI: https://doi.org/10.1002/etc.5620080504
- Roberts and Boyce C. B. C. In: Norris and Ribbons, D. W. (eds.) Methods of Microbiology vol. 7A. Academic Press, New York, 1972.
- Takimotto Y., Matsyda 0. M. T. and Miyamoto M. 1986. Metabolism of several pyrethroid insecticides by carp cyprinus caarpio:Abstract The sixth international congress of pesticides chemistry August 10-15, 1986. International Union of pure and applied toxicology.
- Wouters W. and Bercken J. V. D.1979. Action Pyrethroids. General Pharmacology. 9,387 398. DOI: https://doi.org/10.1016/0306-3623(78)90023-X
- Zitko V., Carson W.G. and Metcalfe C. D. 1977. Toxicity of pyrethroids to juvenile Atlantic salmon. Bull Environ. Contcm. Toxicology. 18, 35-41. DOI: https://doi.org/10.1007/BF01686302
- Zitco V., Mcleese D. W., Metcalfe C. D. and Carlson W. G. I 979. Toxicity of permethrin, decamethrin and related pyretrhroids to Salmon (Sa/mo Saler) and lobster. Bull Environ. Con/am. Toxicol. 21,338-343. DOI: https://doi.org/10.1007/BF01685433
References
Anita Susan T., Veeeraiah K. and Tilak K. S. 1999 a. Biochemical changes in the tissues of the fish Catla catla exposed to fenvaleratse a syntheticpyrethroid. J. Ecobiology 1102), 109-116.
Anita Susan T., Veeraiah K. and Tilak K. S. 1999 b. A study on the Bioaccumulation ofFenvalerate a synthetic pyrethroid in the whole body tissue ofLabeo rohita, Catla catla, Cirrhinus mrigala by GLC. Enviromedia 18(1), 57-59.
Amon 1975. Committee on Methods of Toxicity Tests with Fish, Macroinvertebrates and Amphibuians EPA Oregon 61 pp.
Bradbury S. P. and Coats J. R. 1982. Toxicity of fenvalerat4e to bobwhite quail including brain and liver residues associated with mortality. J. Toxicol. & Environ. Health. 10, 307-319. DOI: https://doi.org/10.1080/15287398209530253
Bradbury S. P., Coats J. R. and Mckim J. M. 1985. Differential toxicity and uptake of two fenvalerate formulation in fathead minoows ( Pimephales promelas) Environ. Toxicol. Chem. 4, 533-541. DOI: https://doi.org/10.1002/etc.5620040413
Bradbury S. P., Coats J. R., Mc Kim J . M . 1986. Toxicokinetics offenvalerate in rainbow trout Salmo gairdneri. Environ. Toxicol Chem. 5, 567- 576. DOI: https://doi.org/10.1002/etc.5620050609
Bradbury S. P., McKim J. M. and Coats J. R. 1987. Physiological response of rainbow torut to acute fenvalerate intoxificatin. Pestic Biochem. Physiol. 27, 275-288. DOI: https://doi.org/10.1016/0048-3575(87)90057-5
Coats J. R. and O'D Jefery N. 1979. Toxicity of four synthetic pyrethroid insecticides to rainbow trout. Bull Environ. Cont@m. Toxicol. 23, 250 -255. DOI: https://doi.org/10.1007/BF01769951
Demoute J. P. 1989. A brief review of the environmental fate and metabolism ofpyrethroids. Pestie. Science. 27,375-385. DOI: https://doi.org/10.1002/ps.2780270406
Edwards R. and Millburn P. 1985. The metaboism and toxicity of insecticides in fish. In: Hutson D. H. and Roberts T. R. (eds) Progress in Pesticides Biochemistry and Toxicology Vo/.5. Insecticides John Wiley and Sons Ltd., New York, pp. 249-274.
Finney D. J. 1971. Probit Analysis. Cambridge University Press, 333pp.
Haya K.1989. Toxicity ofpyrethroid insecticides to fish. Environ. Toxicol. Chem.. 8, 381-391. Murty A. S. 1986. Toxicity ofPesticides to Fish vol. I & II. CRC Press, Inc. DOI: https://doi.org/10.1002/etc.5620080504
Roberts and Boyce C. B. C. In: Norris and Ribbons, D. W. (eds.) Methods of Microbiology vol. 7A. Academic Press, New York, 1972.
Takimotto Y., Matsyda 0. M. T. and Miyamoto M. 1986. Metabolism of several pyrethroid insecticides by carp cyprinus caarpio:Abstract The sixth international congress of pesticides chemistry August 10-15, 1986. International Union of pure and applied toxicology.
Wouters W. and Bercken J. V. D.1979. Action Pyrethroids. General Pharmacology. 9,387 398. DOI: https://doi.org/10.1016/0306-3623(78)90023-X
Zitko V., Carson W.G. and Metcalfe C. D. 1977. Toxicity of pyrethroids to juvenile Atlantic salmon. Bull Environ. Contcm. Toxicology. 18, 35-41. DOI: https://doi.org/10.1007/BF01686302
Zitco V., Mcleese D. W., Metcalfe C. D. and Carlson W. G. I 979. Toxicity of permethrin, decamethrin and related pyretrhroids to Salmon (Sa/mo Saler) and lobster. Bull Environ. Con/am. Toxicol. 21,338-343. DOI: https://doi.org/10.1007/BF01685433