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Abstract
Potassium permanganate is a good oxidizing againt L-citrulline has an – SH group which is rapidly oxidized by potassium permanganate. In the present study it was observed that two equivalent of permanaganate were consumed by five equivalent of L-citrulline. Beside this an attempt to correlate the rate of oxidation with acid concentration, with various Hypothesis for the mechanism of acid catalysis were also observed.
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References
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References
Bunnett. J.F. J. Am. Chem. Soc. 83, 4956 (1961). Bunnett. J.F. J. Am. Soc. 83, 4968(1961). DOI: https://doi.org/10.1021/ja01485a019
Bunnett. J.F. OLSEN, F.P. Can. J. Chem. 44, 1899, 1917(1966). DOI: https://doi.org/10.1139/v66-287
Drummond, A.Y. Waters, W.A.J. Am. Chem. Soc. 2896(1953). Ghosh K.K. and Ghosh S. J. Indian Chem. Soc. (72) 19 (1955) Ghosh K.K. J. Mol. Liquids, 81 135(1999).
Goto A and Krishimoto H, Bull Chem. Soc. Japan, 62 2854 (1989). Iyun J.F. and Onu O.D. Nigerian J. Chem. Research, 3 24(1998). Mallamma, Ananda S. and Rangaswamy Asian J. Chem. 13 543(2001). Marcus Y.J. Chem. Soc. Perkin Trans 2, 1751 (1994).
Mohanty P. Das AC and Nanda R.K.J. Indian Chem. Soc. 62 945(1985). Paul. M.A. LONG, F.A. Chem. Rev, 57, 1(1957). DOI: https://doi.org/10.1021/cr50013a001
Swaminathan K. and Harris G.M.J. Am Chem. Soc. 88 4411(1996). DOI: https://doi.org/10.1021/ja00971a020
VOGEL, A.I. A Text Book of “Quantitative Inorganic Analysis”, p.283, Longman Green, London 1964.
Zucker, L. Hammett, L.P.J. Am. Chem. Soc. 61, (1939) 2791 (1939). DOI: https://doi.org/10.1021/ja01265a066